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MinSeok Jeong 1 Article
Sintering Behavior of M-type Sr-Hexaferrite by MnCO3 Addition
MinSeok Jeong, Changjae You, Jung Young Cho, Kyoung-Seok Moon
J Powder Mater. 2020;27(2):126-131.   Published online April 1, 2020
DOI: https://doi.org/10.4150/KPMI.2020.27.2.126
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The grain growth behavior of M-type Sr hexaferrite (SrM) grains is investigated with the addition of MnCO3. First, the SrM powder is synthesized by a conventional solid-state reaction. The powder compacts of SrM are sintered at 1250°C for 2 h with various amounts of MnCO3 (0, 0.5, 1.0, and 4.0 mol%). There is no secondary solid phase in any of the sintered samples. Relative density increases when MnCO3 is added to the SrM. Obvious abnormal grain growth does not appear in any of the SrM samples with MnCO3. The average grain size increases when 0.5 mol% MnCO3 is added to the SrM. However, as the amount of MnCO3 increase to over 0.5 mol%, the average grain size decreases. These observations allow us to conclude that the growth of SrM grains is governed by the two-dimensional nucleation grain growth mechanism, and the critical driving force for the growth of a grain decreases as the amount of MnCO3 increases.


Journal of Powder Materials : Journal of Powder Materials